Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Bromine | HCID 24408 | — |
| Reactant | 4-Fluoro-3-nitrotoluene | HCID 136287 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | 4-Fluoro-3-nitrobenzyl bromide | HCID 10868208 | — |
Reaction Steps
To a stirred melt of 1-fluoro-4-methyl-2-nitro-benzene (10 g) at 150° C. under a sunlamp was slowly added 3.65 ml of bromine over a 5 hr period. Cooled the brown mixture to 50° C. and poured into 125 ml of hexane. Cooled in an ice bath, filtered, and obtained 10.1 g of 4-bromomethyl-1-fluoro-2-nitro-benzene as white crystals. ##STR127##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05952362 |
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| Source dataset | uspto-grants-1999_09 |
|---|
| ORD ID | ord-b4d2feeb2a3847a8b42cfbaf400104f3 |
|---|
| Source note | uspto-grants-1999_09 |
|---|
