Silver → Silver

HRID 618902Notes

Reaction equation

HRID 618902 reaction equation
[Ag:1].[CH2:2]([OH:4])[CH3:3].[CH:5]([OH:8])([CH3:7])[CH3:6].C(O)CCC.C([CH2:17][C:18](=[O:20])[CH3:19])(=O)C>O.CO>[CH:5]([OH:8])([CH3:7])[CH3:6].[CH:18]([O:20][CH2:3][CH2:2][OH:4])([CH3:17])[CH3:19].[Ag:1]

Participants

6

Reactant 3

HCID 23954SilverHCID 31261AcetylacetoneHCID 18374224HCID 18374224, compound2×

Product 2

HCID 23954SilverHCID 86754524HCID 86754524, compound

Reagents, catalysts & solvents 1

HCID 22242641Methanol--water (1/1)Solvent

Procedure

The same procedures used in Example 1 were repeated except for using, as the medium in which the silver-containing solid content was dispersed, an ethyl alcohol/isopropyl alcohol/butyl alcohol (4:4:1) mixture (Example 2), a 99:1 mixture of an ethyl alcohol/isopropyl alcohol/butyl alcohol (4:4:1) mixture with acetyl acetone (Example 3), an isopropyl alcohol/2-isopropoxy ethanol (80:20) mixture (Example 4) or a water/methyl alcohol (85:15) mixture (Example 5), to thus give each corresponding silver sol.

Workup

  1. additioncontaining solid content
  2. additionwas dispersed

Sources & evidence

ORD record
ord-166eee6042034f51a3bd2eeddcf2a235
Source dataset
uspto-grants-1999_09
Patent number
US05957828

Reaction notes

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