HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl Alcohol → Benzyl Alcohol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl Alcohol | HCID 244 | — |
| Reactant | Methyl 3-hydroxybutyrate, (S)- | HCID 6950307 | — |
| Catalyst | Titanium isopropoxide | HCID 11026 | — |
| Product | Benzyl Alcohol | HCID 244 | — |
| Product | benzyl (S)-3-hydroxybutanoate | HCID 10867200 | — |
Reaction Steps
A chemical reference for desired product was prepared as follows. Methyl (S)-(+)-3-hydroxybutyrate (Aldrich) was dissolved in benzyl alcohol and treated with a catalytic amount of titanium tetraisopropoxide. The mixture was aged at 60° C. for 24 hours. Partial concentration on a rotary evaporator and filtration afforded benzyl (S)-(+)-3-hydroxybutyrate and residual benzyl alcohol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05958743 |
| Source dataset | uspto-grants-1999_09 |
| ORD ID | ord-ca4d322bad8b446db9443d63fa55a6f8 |
| Source note | uspto-grants-1999_09 |