HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → 1-Adamantanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Adamantane | HCID 9238 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Product | Adamantanone | HCID 64151 | 3% |
| Product | 1-Adamantanol | HCID 64152 | 28% |
| Product | 1,3-Adamantanediol | HCID 573829 | 6% |
Reaction Steps
A mixture of 10 millimoles of adamantane, 1 millimole of N-hydroxyphthalimide, 0.05 millimole of acetylacetonatozirconium(IV) Zr(AA)4 and 25 milliliters of acetic acid was stirred at a temperature of 75° C. for 6 hours in an oxygen atmosphere. Adamantane was transformed into 1-adamantanol (yield 28%), 1,3-adamantanediol (yield 6%) and 2-adamantanone (yield 3%) with a transformation rate of 43%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05958821 |
| Source dataset | uspto-grants-1999_09 |
| ORD ID | ord-bfdc538cc5b24b908030e1b3d4699c0b |
| Source note | uspto-grants-1999_09 |