HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → 1-Adamantanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Adamantane | HCID 9238 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Product | Adamantanone | HCID 64151 | 7% |
| Product | 1-Adamantanol | HCID 64152 | 42% |
| Product | 1,3-Adamantanediol | HCID 573829 | 31% |
Reaction Steps
To 25 milliliters of acetic acid were added 10 millimoles of adamantane, 1 millimole of N-hydroxyphthalimide and 0.05 millimole of zirconyl acetate ZrO(OAc)2. The resultant mixture was stirred at a temperature of 75° C. for 6 hours in an oxygen atmosphere. As a result, adamantane was transformed into 1-adamantanol (yield 42%), 1,3-adamantanediol (yield 31%) and 2-adamantanone (yield 7%) with a transformation rate of 91 percent.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05958821 |
| Source dataset | uspto-grants-1999_09 |
| ORD ID | ord-09072ad13214402dba63228fb91df229 |
| Source note | uspto-grants-1999_09 |