Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Fluorene | HCID 6853 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Solvent | Benzonitrile | HCID 7505 | — |
| Product | Fluoreneone | HCID 22281833 | 28% |
Reaction Steps
In an oxygen atmosphere, a mixture of 10 millimoles of fluorene, 1 millimole of N-hydroxyphthalimide, 0.05 millimole of acetylacetonatomanganese Mn(AA)3 and 25 milliliters of benzonitrile was stirred at a temperature of 100° C. for six hours. Products in the reaction mixture were analyzed with gas chromatography, and fluorene was transformed into fluorenone (yield 28%) with a transformation rate of 32 percent.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05958821 |
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| Source dataset | uspto-grants-1999_09 |
|---|
| ORD ID | ord-6bffc9dc383c4de1b12838a27e03ef3c |
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| Source note | uspto-grants-1999_09 |
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