HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → Fluoreneone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Fluorene | HCID 6853 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Solvent | Benzonitrile | HCID 7505 | — |
| Product | Fluoreneone | HCID 22281833 | 30% |
Reaction Steps
Ten (10) millimoles of fluorene, 1 millimole of N-hydroxyphthalimide and 0.05 millimole of acetylacetonatomanganese Mn(AA)2 were added to 25 milliliters of benzonitrile. The resultant mixture was stirred in an oxygen atmosphere at a temperature of 100° C. for six hours. A product in the reaction mixture was analyzed by means of gas chromatography, and fluorene was transformed into fluorenone (yield 30%) with a transformation rate of 38 percent.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05958821 |
| Source dataset | uspto-grants-1999_09 |
| ORD ID | ord-c249708c02f64dfc9f12a2463a8d9653 |
| Source note | uspto-grants-1999_09 |