HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-(2,6-Dimethyl-3-nitrophenyl)-1,3-dioxolane → 2-(3-Amino-2,6-dimethylphenyl)-1,3-dioxolane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-(2,6-Dimethyl-3-nitrophenyl)-1,3-dioxolane | HCID 21847033 | — |
| Catalyst | Platinum oxide (PtO) | HCID 82844 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | 2-(3-Amino-2,6-dimethylphenyl)-1,3-dioxolane | HCID 21847039 | 100.5% |
Reaction Steps
A solution of 2.7 g of 2-(2,6-dimethyl-3-nitrophenyl)-1,3-dioxolane in 30 ml of ethyl acetate was hydrogenated in the presence of 0.2 g of platinum oxide for 45 minutes. The catalyst was filtered off and the solution was concentrated to a crystalline residue. Recrystallization from hexane yielded 2.35 g of 2-(3-amino-2,6-dimethylphenyl)-1,3-dioxolane, m.p. 100-103° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05959113 |
| Source dataset | uspto-grants-1999_09 |
| ORD ID | ord-2144cbffdd4549fb976991804cbf151a |
| Source note | uspto-grants-1999_09 |