HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl Peroxide → 1-(broMoMethyl)-4-((trifluoroMethyl)sulfonyl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl Peroxide | HCID 7187 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 1-methyl-4-(trifluoromethylsulfonyl)benzene | HCID 882246 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 1-(broMoMethyl)-4-((trifluoroMethyl)sulfonyl)benzene | HCID 15323598 | — |
Reaction Steps
A stirred solution of 22.4 g (0.1 mole) of 4-triflyltoluene, 178 g (0.1 mole) of N-bromosuccinimide, and 0.48 g (0.2 mole %) of benzoyl peroxide in carbon tetrachloride is heated at reflux for 20 hours. After cooling to room temperature, the reaction is diluted by the addition of carbon tetrachloride, and the solid byproducts are removed by filtration. The filtrate is concentrated in vacuo, and the product is purified by recrystallization from benzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05247042 |
| Source dataset | uspto-grants-1993_09 |
| ORD ID | ord-7218c825a19c4b7087dc142778ad78c1 |
| Source note | uspto-grants-1993_09 |