1-Chloro-4-nitrobenzene → HCID 19860671, compound

HRID 620458Notes

Reaction equation

HRID 620458 reaction equation
[CH3:1][C:2]([CH2:7][CH2:8][CH3:9])([CH2:5][OH:6])[CH2:3][OH:4].[N+:10]([C:13]1[CH:18]=[CH:17][C:16](Cl)=[CH:15][CH:14]=1)([O-:12])=[O:11].[OH-:20].[Na+]>CS(C)=O>[N+:10]([C:13]1[CH:18]=[CH:17][C:16]([O:4][CH2:3][C:2]([CH3:1])([CH2:7][CH2:8][CH3:9])[CH2:5][O:6][C:16]2[CH:17]=[CH:18][C:13]([N+:10]([O-:11])=[O:20])=[CH:14][CH:15]=2)=[CH:15][CH:14]=1)([O-:12])=[O:11]

Participants

5

Reactant 3

HCID 74741-Chloro-4-nitrobenzeneHCID 14798Sodium HydroxideHCID 662202-Methyl-2-propylpropane-1,3-diol

Product 1

HCID 19860671HCID 19860671, compound

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

132 g (1 mol) 2-methyl-2-propyl-1,3-dihydroxypropane, 346.5 g (2.2 mols) 4-nitrochlorobenzene and 140 g powdered sodium hydroxide were reacted in the same manner as was described in Example 1 in 600 ml DMSO.

Workup

  1. customwere reacted in the same manner

Sources & evidence

ORD record
ord-de0b13190d0c4c2aa7924c23b07cb4a9
Source dataset
uspto-grants-1989_04
Patent number
US04820866

Reaction notes

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