HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 620697Erstellt: 25. Oktober 2026
Dimethylformamide → Ethyl 2-(3-nitrophenoxy)tetradecanoate
https://huagongshe.com/reaction/620697
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Dimethylformamide | HCID 6228 | — |
| Edukt | 3-Nitrophenol | HCID 11137 | — |
| Edukt | Potassium Carbonate | HCID 11430 | — |
| Edukt | Tetradecanoic acid, 2-bromo-, ethyl ester | HCID 85791 | — |
| Lösungsmittel | Acetic Acid | HCID 176 | — |
| Lösungsmittel | Water | HCID 962 | — |
| Produkt | Ethyl 2-(3-nitrophenoxy)tetradecanoate | HCID 14122414 | — |
Reaktionsschritte
A mixture of 250 g (1.79 mol) of m-nitrophenol, 602 g (1.79 mol) of Alphabromo-myristic acid ethyl ester, 248 g (1.79 mol) of potassium carbonate, and 1350 ml of dimethylformamide is heated to 80° C. for 3 h with stirring. The mixture is then poured out slowly into a mixture of 2300 ml of water and 250 ml of acetic acid. The product is extracted with dichloromethane. The solvent is removed by evaporation.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US04822729 |
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| Quelldatensatz | uspto-grants-1989_04 |
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| ORD ID | ord-8e1268a3ad914c10b3412d4df8d51779 |
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| Quellennotiz | uspto-grants-1989_04 |
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