HCID 54516582, compound → HCID 54361923, compound

HRID 620944Notes

Reaction equation

HRID 620944 reaction equation
[CH3:1][C:2](=[CH:19][CH2:20][CH2:21][C:22]([CH3:25])=[CH:23][CH3:24])[CH2:3][O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[C:11](=[CH:16][O:17][CH3:18])[C:12]([O:14][CH3:15])=[O:13].[H][H]>CO.[Pd]>[CH3:1][CH:2]([CH2:19][CH2:20][CH2:21][CH:22]([CH3:25])[CH2:23][CH3:24])[CH2:3][O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[C:11](=[CH:16][O:17][CH3:18])[C:12]([O:14][CH3:15])=[O:13]

Participants

5

Reactant 2

HCID 54516582HCID 54516582, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 54361923HCID 54361923, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

3.2 g of methyl α-(2-(2,6-dimethylocta-2,6-dienyloxy)phenyl)-β-methoxyacrylate are dissolved in 70 ml of methanol, and 0.2 g of palladium on active carbon is added. At room temperature, hydrogen is passed with stirring through the suspension until no further gas is absorbed. The solution is separated from the catalyst and evaporated. This give 3.1 g of an oil.

Workup

  1. customAt room temperature
  2. customis absorbed
  3. customThe solution is separated from the catalyst
  4. customevaporated

Sources & evidence

ORD record
ord-6861a35b7d6f471bb4706c90a05877d8
Source dataset
uspto-grants-1989_04
Patent number
US04822908

Reaction notes

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