HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonia → HCID 53866468, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | Dimethyl Sulfate | HCID 6497 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | HCID 21245515 | HCID 21245515 | — |
| Solvent | Acetone | HCID 180 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 53866468 | HCID 53866468 | 82.4% |
Reaction Steps
10 g of methyl α formyl-(2-butoxyphenyl)acetate are dissolved in 100 ml of acetone. 15 g of potassium carbonate are added, followed gradually with stirring by an equimolar amount of dimethyl sulfate. After 12 hours of refluxing, 50 ml of H2O are added, followed carefully by 30 ml of concentrated NH3 solution. After 2 hours of stirring, about 100 ml of solvent are drawn off, poured onto ice and extracted with dichloromethane. Drying of the organic phase leaves 8.7 g of oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04822908 |
| Source dataset | uspto-grants-1989_04 |
| ORD ID | ord-4241f23824a24496b35bb91d7cdfdb3a |
| Source note | uspto-grants-1989_04 |