HCID 3760131, compound → HCID 1787923, compound

HRID 621406Notes

Reaction equation

HRID 621406 reaction equation
[C:1]1([CH:7]=[CH:8][C:9]([NH:11][NH:12][C:13]([O:15][CH3:16])=[O:14])=[O:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>[Pd].CO>[C:1]1([CH2:7][CH2:8][C:9]([NH:11][NH:12][C:13]([O:15][CH3:16])=[O:14])=[O:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 1

HCID 3760131HCID 3760131, compound

Product 1

HCID 1787923HCID 1787923, compoundYield 98.2%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

22.0 g. (0.1 mole) of methyl 3-(β-phenylacryloyl)-carbazate are dissolved in 300 ml. of methanol and the solution is hydrogenated in the presence of 0.2 g. of a palladium-charcoal catalyst. The solution is evaporated. Thus 21.8 g. of the white crystalline desired compound are obtained. Yield: 98.2%. M.p.: 118° C.

Workup

  1. customThe solution is evaporated

Sources & evidence

ORD record
ord-095c9dd831f24332844d4407d75e4bd2
Source dataset
uspto-grants-1989_04
Patent number
US04824670

Reaction notes

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