HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thiophosgene → HCID 22155444, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thiophosgene | HCID 10040 | — |
| Reactant | 6-Methoxy-3-pyridinylamine | HCID 81121 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 22155444 | HCID 22155444 | 47.4% |
Reaction Steps
5-Amino-2-methoxypyridine (11 ml, 0.10 mol) is added dropwise at reflux, with stirring to a solution of thiophosgene (8.4 ml, 0.11 mol) in methylene chloride. Refluxing is continued for a further hour and cooled to room temperature. The resulting solid is filtered off, washed with ether to give 9.6 g of the title intermediate product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04824854 |
| Source dataset | uspto-grants-1989_04 |
| ORD ID | ord-238af5edae374584a9e3243c1e744763 |
| Source note | uspto-grants-1989_04 |