Oxygen → 3-Ethyloxetane-3-carboxylic acid

HRID 621753Notes

Reaction equation

[O:1]=O.[CH2:3]([C:5]1([CH2:9][OH:10])[CH2:8][O:7][CH2:6]1)[CH3:4]>>[CH2:3]([C:5]1([C:9]([OH:1])=[O:10])[CH2:8][O:7][CH2:6]1)[CH3:4]

Participants

Reactant 2

HCID 977Oxygen

HCID 76444Oxt-101

Product 1

HCID 140289983-Ethyloxetane-3-carboxylic acidYield 86.2%

Procedure

The procedure as in Example 10 is carried out, but at an oxidation temperature of 40° C. After 2 hours, 0.8 mol of oxygen have been taken up per mol of 3-ethyl-3-hydroxymethyl-oxetane. After working up, 3-ethyl-oxetane-3-carboxylic acid is obtained in a yield of 86.2% of theory.

Workup

customat an oxidation temperature of 40° C

Sources & evidence

ORD record: ord-3c69a5028921493d9e87b9c8fbc5790d
Source dataset: uspto-grants-1989_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04824975

Reaction notes

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