HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 622111Generated: October 30, 2026
1,4-Dimethyl-5-hydroxymethyl-2-(4-methoxybenzylthio)imidazole → 1,4-Dimethyl-5-formyl-2-(4-methoxybenzylthio)imidazole
https://huagongshe.com/reaction/622111
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1,4-Dimethyl-5-hydroxymethyl-2-(4-methoxybenzylthio)imidazole | HCID 14257103 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1,4-Dimethyl-5-formyl-2-(4-methoxybenzylthio)imidazole | HCID 14257104 | — |
Reaction Steps
A mixture of 1,4-dimethyl-5-hydroxymethyl-2-(4-methoxybenzylthio)imidazole (1 g, 4 mmoles) and manganese dioxide (1.3 g, 15 mmoles) in methylene chloride (50 ml) was stirred at 25° C. for 16 hours. The mixture was filtered and the filtrate concentrated in vacuo to give 1,4-dimethyl-5-formyl-2-(4-methoxybenzylthio)imidazole.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04769386 |
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| Source dataset | uspto-grants-1988_09 |
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| ORD ID | ord-caf764b1497843168d8abbe2f7e8a440 |
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| Source note | uspto-grants-1988_09 |
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