HuagongsheHuagongshe Chemistry Print Report · For research reference only
H-Phe-Pro-OMe → H-Glu(Bzl)-Pro-OMe trifluoroacetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | H-Phe-Pro-OMe | HCID 11311926 | — |
| Reactant | Methyl N6-((benzyloxy)carbonyl)-L-lysyl-L-prolinate, 2,2,2-trifluoroacetate salt | HCID 131667640 | — |
| Product | H-Glu(Bzl)-Pro-OMe trifluoroacetate | HCID 131715717 | — |
Reaction Steps
Instead of H-Phe-Pro-OMe (1 equivalent) and TEA (1 equivalent) in (b), (c) H-Lys(Z)-Pro-OMe trifluoroacetate (1 equivalent) and TEA (2 equivalents) were used to obtain (c') oleoyl-Lys(Z)-Pro-OMe (SUAM 1197) as an oil, and (d) H-Glu(Bzl)-Pro-OMe trifluoroacetate (1 equivalent) and TEA (2-equivalents) were used to obtain (d') oleoyl-Glu(Bzl)-Pro-OMe (SUAM 1196) as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04772587 |
| Source dataset | uspto-grants-1988_09 |
| ORD ID | ord-3785bccf6be04a3d96a19d4c5a08f59e |
| Source note | uspto-grants-1988_09 |