Chlorosulfonic acid → HCID 21291491, compound

HRID 622686Notes

Reaction equation

HRID 622686 reaction equation
[CH3:1][N:2]1[C:11]2[C:6](=[CH:7][CH:8]=[C:9]([CH3:12])[CH:10]=2)[C:5](=[O:13])[CH:4]=[CH:3]1.[Cl:14][S:15](O)(=[O:17])=[O:16]>>[CH3:1][N:2]1[C:11]2[C:6](=[CH:7][CH:8]=[C:9]([CH3:12])[CH:10]=2)[C:5](=[O:13])[C:4]([S:15]([Cl:14])(=[O:17])=[O:16])=[CH:3]1

Participants

3

Reactant 2

HCID 24638Chlorosulfonic acidHCID 21291478HCID 21291478, compound

Product 1

HCID 21291491HCID 21291491, compound

Procedure

1,7-Dimethyl-4-quinolone (4.31 g) was stirred with chlorosulphonic acid (11.95 ml) at 140° for 2.5 hours and then cooled to room temperature and poured carefully into ice water (1 liter). The resulting white solid was collected, washed with water and dried to give the novel compound 1,7-dimethyl-4-oxo-1,4-dihydroquinoline-3-sulphonyl chloride, m.p. >300°.

Workup

  1. customThe resulting white solid was collected
  2. washwashed with water
  3. customdried

Sources & evidence

ORD record
ord-51fd49c6ad994aedbbcc07948012cc5d
Source dataset
uspto-grants-1988_09
Patent number
US04772614

Reaction notes

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