Benzyl trifluoromethanesulfonate → 3-Benzyl-2-methylbenzotellurazolium Trifluoromethanesulfonate

HRID 622849Notes

Reaction equation

HRID 622849 reaction equation
[CH3:1][C:2]1[Te:3][C:4]2[CH:10]=[CH:9][CH:8]=[CH:7][C:5]=2[N:6]=1.[F:11][C:12]([F:25])([F:24])[S:13]([O:16][CH2:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)(=[O:15])=[O:14].[Te]1C2C=CC=CC=2N=C1>ClCCl.C(Cl)(Cl)(Cl)Cl>[F:11][C:12]([F:25])([F:24])[S:13]([O-:16])(=[O:15])=[O:14].[CH2:17]([N+:6]1[C:5]2[CH:7]=[CH:8][CH:9]=[CH:10][C:4]=2[Te:3][C:2]=1[CH3:1])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1

Participants

6

Reactant 3

HCID 11096711Benzyl trifluoromethanesulfonateHCID 132147951,3-BenzotellurazoleHCID 132147962-Methyl-1,3-benzotellurazole

Product 1

HCID 139312323-Benzyl-2-methylbenzotellurazolium Trifluoromethanesulfonate

Reagents, catalysts & solvents 2

HCID 5943Carbon TetrachlorideSolventHCID 6344DichloromethaneSolvent

Procedure

2-Methylbenzotellurazole (Example 18) (0.81 g), 0.0033 mole) was dissolved in dichloromethane (25 ml). The solution of benzyl trifluoromethanesulfonate (0.004 mole) in carbon tetrachloride, prepared as described above, was placed in a dropping funnel and added at room temperature under a nitrogen atmosphere to the benzotellurazole solution. Stirring was continued for 18 hours at room temperature after the addition was complete, maintaining a nitrogen atmosphere. The solid was isolated by filtration, washed with diethyl ether, and dried at room temperature under a vacuum. Yield 0.30 g (19% of theory) of a white powder, m.p. 120°-122° C. The infrared, nuclear magnetic resonance, and mass spectra of this compound were in agreement with that expected for the structural formula.

Workup

  1. customwas placed in a dropping funnel
  2. additionafter the addition
  3. temperaturemaintaining a nitrogen atmosphere
  4. customThe solid was isolated by filtration
  5. washwashed with diethyl ether
  6. customdried at room temperature under a vacuum

Sources & evidence

ORD record
ord-e4b5cf6ddcd344cd8f23044260c3f17e
Source dataset
uspto-grants-1988_09
Patent number
US04772715

Reaction notes

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