Sodium Hydroxide → HCID 178418584, compound

HRID 622896Notes

Reaction equation

HRID 622896 reaction equation
[NH2:1][CH2:2][CH:3]([C:8]1[CH:13]=[CH:12][C:11]([Cl:14])=[CH:10][CH:9]=1)[CH2:4][P:5]([OH:7])[OH:6].[OH-].[Na+:16]>>[NH2:1][CH2:2][CH:3]([C:8]1[CH:13]=[CH:12][C:11]([Cl:14])=[CH:10][CH:9]=1)[CH2:4][PH:5](=[O:6])[O-:7].[Na+:16]

Participants

3

Reactant 2

HCID 14798Sodium HydroxideHCID 117761763-Amino-2-(4-chlorophenyl)propylphosphonous acid

Product 1

HCID 178418584HCID 178418584, compound

Procedure

A solution of 0.25 g of 3-amino-2-(4-chlorophenyl)propylphosphonous acid in 10 ml of 0.1M sodium hydroxide solution is stirred at room temperature for a period of 1 hour, and then concentrated under reduced pressure to give sodium 3-amino-2-(4-chlorophenyl)propylphosphinate as a hygroscopic solid, 31P=+26.0 ppm (D2O).

Workup

  1. concentrationconcentrated under reduced pressure

Sources & evidence

ORD record
ord-ecede01b0ebd41c4ae01a80f73da8ef2
Source dataset
uspto-grants-1988_09
Patent number
US04772738

Reaction notes

Loading…