HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bis(eta-cyclopentadienyl) iron → Mesitylene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bis(eta-cyclopentadienyl) iron | HCID 7611 | — |
| Reactant | Mesitylene | HCID 7947 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Catalyst | Zirconium chloride (ZrCl4), (T-4)- | HCID 9856075 | — |
| Product | Mesitylene | HCID 7947 | — |
| Product | HCID 178418685 | HCID 178418685 | — |
Reaction Steps
In accordance with the procedure of Example 4, 10 g (0.043 mol) of ZrCl4 are added at 60° C. under argon over the course of 1 hour and 10 minutes to a stirred mixture of 60 ml of mesitylene, 8 g (0.043 mol) of ferrocene and 5.7 g (0.043 mol) of sublimed AlCl3. Working up is effected as in Example 4, affording 20.1 g (83.4% of theory) of crude (η6 -mesitylene)-η5 -(cyclopentadienyl)-iron(II) tetrapnenylborate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05247107 |
| Source dataset | uspto-grants-1993_09 |
| ORD ID | ord-6e509896da094dc58fef5e22f2f94349 |
| Source note | uspto-grants-1993_09 |