HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl Acrylate → 3-Cyclohexene-1-carboxylic acid, 3,4-dimethyl-, methyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl Acrylate | HCID 7294 | — |
| Reactant | 2,3-Dimethyl-1,3-butadiene | HCID 10566 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 3-Cyclohexene-1-carboxylic acid, 3,4-dimethyl-, methyl ester | HCID 572667 | 87% |
Reaction Steps
A solution of methyl acrylate (1 eq.) and 2,3-dimethylbuta-1,3-diene (1.1 eq.) in toluene (2M) was pumped through a heated coil reactor at 220° C. with a residence time of 17 minutes. The resulting mixture was concentrated under reduced pressure and yielded the product as colorless oil (87% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09303232B2 |
| Source dataset | uspto-grants-2016_04 |
| ORD ID | ord-a794476bcefe477eb7ca51f1272dffef |
| Source note | uspto-grants-2016_04 |