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HRID627144

反应详情

EQUATION

反应方程式

HRID 627144 的结构方程式

REACTANTS

反应物

4
结构：C=CCONS(=O)(=O)c1ccccc1[N+](=O)[O-]
HCID15497911

2-Nitro-N-[(prop-2-en-1-yl)oxy]benzene-1-sulfonamide

C9H10N2O5S

2 次

结构：C=CCONS(=O)(=O)c1ccc([N+](=O)[O-])cc1[N+](=O)[O-]
HCID89851401

未命名化合物

结构：CC(C)(C)OC(=O)N1C[C@@H](O)C(C(N)=O)=C[C@H]1CO[Si](C)(C)C(C)(C)C
HCID89852199

未命名化合物

3 次

结构：C=CCON([C@H]1CN(C(=O)OC(C)(C)C)[C@H](CO[Si](C)(C)C(C)(C)C)C=C1C(N)=O)S(=O)(=O)c1ccc([N+](=O)[O-])cc1[N+](=O)[O-]
HCID89852350

未命名化合物

PRODUCTS

生成物

1
结构：C=CCON([C@H]1CN(C(=O)OC(C)(C)C)[C@H](CO[Si](C)(C)C(C)(C)C)C=C1C(N)=O)S(=O)(=O)c1ccccc1[N+](=O)[O-]
HCID89852378

未命名化合物

收率 74%

PROCEDURE

实验过程

The title compound (4.0 g, 74%) was prepared from (2S,5S)-tert-butyl 2-((tert-butyldimethylsilyloxy)methyl)-4-carbamoyl-5-hydroxy-5,6-dihydropyridine-1(2H)-carboxylate (Intermediate 104, 3.36 g, 8.69 mmol) using the same procedure to prepare Intermediate 105 from Intermediate 104, but using N-(allyloxy)-2-nitrobenzenesulfonamide (Intermediate 9, 2.24 g, 8.69 mmol) as a reagent in place of N-(allyloxy)-2,4-dinitrobenzenesulfonamide.