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HRID627211

反应详情

EQUATION

反应方程式

HRID 627211 的结构方程式

REACTANTS

反应物

2
结构：C=CCON([C@H]1CN(C(=O)OC(C)(C)C)[C@H](C(N)=O)C(C)=C1C)S(=O)(=O)c1ccccc1[N+](=O)[O-]
HCID89852446

未命名化合物

2 次

结构：C=CCON([C@H]1CN[C@H](C(N)=O)C=C1C)S(=O)(=O)c1ccccc1[N+](=O)[O-]
HCID117940244

未命名化合物

PRODUCTS

生成物

1
结构：C=CCON([C@H]1CN[C@H](C(N)=O)C(C)=C1C)S(=O)(=O)c1ccccc1[N+](=O)[O-]
HCID89852316

未命名化合物

收率 75.1%

PROCEDURE

实验过程

The title compound was prepared from (2S,5R)-tert-butyl 5-(N-(allyloxy)-2-nitrophenylsulfonamido)-2-carbamoyl-3,4-dimethyl-5,6-dihydropyridine-1(2H)-carboxylate (Intermediate 195, 1.36 g, 2.66 mmol) following the procedure described for Intermediate 21. The workup yielded an organic layer that was dried over magnesium sulfate, filtered and concentrated to afford the desired product as a light pink solid (0.82 g, 75%).

WORKUP

后处理

  1. customThe workup yielded an organic layer that
  2. dry with materialwas dried over magnesium sulfate
  3. filtrationfiltered
  4. concentrationconcentrated