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HRID627219

反应详情

EQUATION

反应方程式

HRID 627219 的结构方程式

REACTANTS

反应物

2
结构：CC1=C[C@@H](CO[Si](C)(C)C(C)(C)C)N(C(=O)OC(C)(C)C)CC1=O
HCID89852373

未命名化合物

结构：CC=CC(=O)CN(C(=O)OC(C)(C)C)[C@H](CO[Si](C)(C)C(C)(C)C)C(=CC)CC
HCID131735293

未命名化合物

2 次

PRODUCTS

生成物

1
结构：CCC1=CC(=O)CN(C(=O)OC(C)(C)C)[C@@H]1CO[Si](C)(C)C(C)(C)C
HCID89852241

未命名化合物

收率 54.2%

CONDITIONS

反应条件

温度
86 °C

PROCEDURE

实验过程

The title compound was prepared from (S)-tert-butyl 1-(tert-butyldimethylsilyloxy)-3-ethylpent-3-en-2-yl(2-oxopent-3-enyl)carbamate (Intermediate 206, 10.95 g, 25.72 mmol) according to the procedure described for Intermediate 7, except the reaction was heated at 86° C. for 6 days. Silica gel chromatography (0-10% ethyl acetate/hexanes) afforded the title compound (5.15 g, 54.1%) as a light yellow oil.