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HRID627226

反应详情

EQUATION

反应方程式

HRID 627226 的结构方程式

REACTANTS

反应物

2
结构：C=CCON([C@@H]1C=C(CC)[C@@H](C(N)=O)NC1)S(=O)(=O)c1ccccc1[N+](=O)[O-]
HCID89852009

未命名化合物

2 次

结构：C=CCON[C@H]1CN[C@H](CO[Si](C)(C)C(C)(C)C)C=C1C
HCID131735277

未命名化合物

PRODUCTS

生成物

1
结构：C=CCONC1C=C(CC)[C@H](C(N)=O)NC1
HCID89852076

未命名化合物

收率 74.3%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO.ClCCl
溶剂HCID21226129

未命名化合物

PROCEDURE

实验过程

The title compound was prepared from (2S,5R)-5-(N-(allyloxy)-2-nitrophenylsulfonamido)-3-ethyl-1,2,5,6-tetrahydropyridine-2-carboxamide (Intermediate 213, 0.87 g, 2.12 mmol) following the procedure described for Intermediate 12. Silica gel chromatography (0%-8% methanol/dichloromethane) afforded the title compound (0.355 g, 74.3%) as an off-white solid upon drying on high-vacuum.