HRID627248

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C=C(C1CC1)[C@@H](CO[Si](C)(C)C(C)(C)C)N(CC(=O)/C=C/C)C(=O)OC(C)(C)C

HCID89851850

未命名化合物

2 次

结构：CC1=C[C@@H](CO[Si](C)(C)C(C)(C)C)N(C(=O)OC(C)(C)C)CC1=O

HCID89852373

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)N1CC(=O)C=C(C2CC2)[C@H]1CO[Si](C)(C)C(C)(C)C

HCID89851848

未命名化合物

CONDITIONS

反应条件

温度: 110 °C

PROCEDURE

实验过程

The title compound was prepared from (S,E)-tert-butyl 1-(tert-butyldimethylsilyloxy)-3-cyclopropylbut-3-en-2-yl(2-oxopent-3-enyl)carbamate (Intermediate 236, 4 g, 9.44 mmol) following the procedure described for Intermediate 7, except the reaction mixture was heated at 110° C. overnight. The desired product was obtained as a light brown oil (2.97 g, 82%).