HRID627270

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C=C[C@@H](CO[Si](C)(C)C(C)(C)C)N(CC(=O)C(=C)C1CC1)C(=O)OC(C)(C)C

HCID89852359

未命名化合物

2 次

结构：CC1=C[C@@H](CO[Si](C)(C)C(C)(C)C)N(C(=O)OC(C)(C)C)CC1=O

HCID89852373

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)N1CC(=O)C(C2CC2)=C[C@H]1CO[Si](C)(C)C(C)(C)C

HCID89852228

未命名化合物

PROCEDURE

实验过程

The title compound was prepared from (S)-tert-butyl 1-(tert-butyldimethylsilyloxy)but-3-en-2-yl(3-cyclopropyl-2-oxobut-3-enyl)carbamate (Intermediate 262, 5.16 g, 12.60 mmol) following the procedure described for Intermediate 7, except the reaction mixture was heated at 85° C. overnight The desired product was obtained as a light yellow oil (3.82 g, 79%).