Triacetoxyperiodinane → HCID 86673489, compound

Participants

Reaction Steps

To a suspension of Dess-Martin periodinane in CH2Cl2 (15%, 11.2 ml, 1.1 eq) was added to a stirred solution of (2-chloro-5-ethoxy-6-morpholin-4-yl-pyrimidin-4-yl)-methanol (1.13 g, 1 eq.) in CH2Cl2 (20 ml) and the mixture was reacted at r.t. for 2 h. The mixture was quenched with NaHCO3(sat), extracted with EA, and washed with brine. The crude was purified by chromatography to give a product (1.08 g, 80.8%).

Provenance & Evidence