HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-Bromo-benzo[b]thiophene-2-carbaldehyde → 5-Butyl-2-formylbenzothiophene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-Bromo-benzo[b]thiophene-2-carbaldehyde | HCID 618035 | — |
| Reactant | Potassium Butyltrifluoroborate | HCID 23693579 | — |
| Product | 5-Butyl-2-formylbenzothiophene | HCID 118228959 | 85% |
Reaction Steps
The compound was prepared as in Example 3.1 using 5-bromo-2-formylbenzothiophene (241 mg, 1.0 mmol) in place of 5-bromo-2-formylfuran and potassium butyltrifluoroborate (246 mg, 1.5 mmol) in place of hexylboronic acid to give 5-butyl-2-formylbenzothiophene (185 mg, 85%). Used without further characterization.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09315495B2 |
| Source dataset | uspto-grants-2016_04 |
| ORD ID | ord-0ad649dbcba6473798dfb99177ece574 |
| Source note | uspto-grants-2016_04 |