HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromo-4-iodobenzene → N-(4-bromophenyl)-N-phenyldibenzo[b,d]furan-2-amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromo-4-iodobenzene | HCID 11522 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | Sodium t-butoxide | HCID 23676156 | — |
| Reactant | N-phenyl-2-Dibenzofuranamine | HCID 67204676 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | N-(4-bromophenyl)-N-phenyldibenzo[b,d]furan-2-amine | HCID 89769866 | — |
Reaction Steps
N-phenyldibenzo[b,d]furan-2-amine (5.0 g, 19.3 mmol), and 1-bromo-4-iodobenzene (10.9 g, 38.6 mmol) were mixed in 100 mL of toluene. The solution was bubbled with nitrogen for 15 min. Pd(OAc)2 (0.22 g, 1.0 mmol), triphenylphosphine (0.51 g, 1.9 mmol) and sodium t-butoxide (2.2 g, 23.1 mmol) were added. The mixture was refluxed overnight under nitrogen.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09324949B2 |
| Source dataset | uspto-grants-2016_04 |
| ORD ID | ord-1c5cdda3037f445b8d564d9d3d53e2d2 |
| Source note | uspto-grants-2016_04 |