HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cornforth reagent → HCID 86756381, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cornforth reagent | HCID 2724130 | — |
| Reactant | HCID 54168262 | HCID 54168262 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 86756381 | HCID 86756381 | 38.4% |
Reaction Steps
410 mg of 5,5,9-Trimethyl-dec-7-ene-1,9-diol (1.93 mmol) ) was oxidized by reaction with 2.76 g of pyridinium-dichromate (3.8 eq.) in 61 ml of CH2Cl2 at room temperature over night. Filtration over a pad of Celite, removal of the solvent and flash chromatography (SiO2, hexane/ethylacetate=8/2) furnished 245 mg of the title compound as colourless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06184422B2 |
| Source dataset | uspto-grants-2001_02 |
| ORD ID | ord-e66e902802d94f7785ba6e382b6d91de |
| Source note | uspto-grants-2001_02 |