HCID 69965193, compound → HCID 86756399, compound

HRID 635142Notes

Reaction equation

[CH2:1]([O:6][C@@H:7]1[CH2:12][O:11][C@@H:10]([C:13]2[CH:18]=[CH:17][C:16]([C:19]34[CH2:26][CH2:25][C:22]([CH2:27][CH2:28][CH3:29])([CH2:23][CH2:24]3)[CH2:21][CH2:20]4)=[CH:15][CH:14]=2)[CH2:9][O:8]1)/[CH:2]=[CH:3]/[CH2:4]C.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCC)(CC3)CC4)=CC=2)CO1)/C=C/CCCC.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCC)(CC3)CC4)=CC=2)CO1)/C=C/CCCCC.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCC)(CC3)CC4)=CC=2)CO1)/C=C/C.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCC)(CC3)CC4)=CC=2)CO1)/C=C/CC.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCC)(CC3)CC4)=CC=2)CO1)/C=C/CCCC.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCC)(CC3)CC4)=CC=2)CO1)/C=C/CCCCC.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCC)(CC3)CC4)=CC=2)CO1)C/C=C\CC.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCC)(CC3)CC4)=CC=2)CO1)CC/C=C/C.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCC)(CC3)CC4)=CC=2)CO1)CCCC=C.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCCCC)(CC3)CC4)=CC=2)CO1)/C=C/C.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCCCC)(CC3)CC4)=CC=2)CO1)/C=C/CC.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCCCC)(CC3)CC4)=CC=2)CO1)/C=C/CCCC.C(O[C@@H]1CO[C@@H](C2C=CC(C34CCC(CCCCCCC)(CC3)CC4)=CC=2)CO1)/C=C/CCCCC>>[CH2:1]([O:6][C@@H:7]1[CH2:12][O:11][C@@H:10]([C:13]2[CH:14]=[CH:15][C:16]([C:19]34[CH2:24][CH2:23][C:22]([CH2:27][CH2:28][CH3:29])([CH2:21][CH2:20]3)[CH2:25][CH2:26]4)=[CH:17][CH:18]=2)[CH2:9][O:8]1)/[CH:2]=[CH:3]/[CH3:4]

Participants

Reactant 14

HCID 69965193HCID 69965193, compound

HCID 86756400HCID 86756400, compound

HCID 86756401HCID 86756401, compound

HCID 86756402HCID 86756402, compound

HCID 86756403HCID 86756403, compound

HCID 86756404HCID 86756404, compound

HCID 86756405HCID 86756405, compound

HCID 86756406HCID 86756406, compound

HCID 86756407HCID 86756407, compound

HCID 86756408HCID 86756408, compound

HCID 86756409HCID 86756409, compound

HCID 86756410HCID 86756410, compound

HCID 86756411HCID 86756411, compound

HCID 86756412HCID 86756412, compound

Product 1

HCID 86756399HCID 86756399, compound

Procedure

1-[4-(trans-5-[(E)-Pent-2-enyloxy]dioxan-2-yl)phenyl]-4-propylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Hept-2-enyloxy]dioxan-2-yl)phenyl]-4-propylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Oct-2-enyloxy]dioxan-2-yl)phenyl]-4-propylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-But-2-enyloxy]dioxan-2-yl)phenyl]-4-pentylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Pent-2-enyloxy]dioxan-2-yl)phenyl]-4-pentylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Hept-2-enyloxy]dioxan-2-yl)phenyl]-4-pentylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Oct-2-enyloxy]dioxan-2-yl)phenyl]-4-pentylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(Z)-Hex-3-enyloxy]dioxan-2-yl)phenyl]-4-pentylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Hex-4-enyloxy]dioxan-2-yl)phenyl]-4-pentylbicyclo[2.2.2]octane. 1-[4-(trans-5-[Hex-5-enyloxy]dioxan-2-yl)phenyl]-4-pentylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-But-2-enyloxy]dioxan-2-yl)phenyl]-4-heptylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Pent-2-enyloxy]dioxan-2-yl)phenyl]-4-heptylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Hept-2-enyloxy]dioxan-2-yl)phenyl]-4-heptylbicyclo[2.2.2]octane. 1-[4-(trans-5-[(E)-Oct-2-enyloxy]dioxan-2-yl)phenyl]-4-heptylbicyclo[2.2.2]octane.

Sources & evidence

ORD record: ord-1d274981b9c049309b7825d7cf7fa92e
Source dataset: uspto-grants-2001_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06187393B1

Reaction notes

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