HCID 69962011, compound → HCID 69962512, compound

HRID 635145Notes

Reaction equation

[C:1]([O:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]23[CH2:21][CH2:20][C:17]([CH2:22][CH2:23][CH3:24])([CH2:18][CH2:19]2)[CH2:16][CH2:15]3)=[C:10]([F:25])[C:9]=1[F:26])(=[O:6])/[CH:2]=[CH:3]/[CH2:4]C.C(OC1C=CC(C23CCC(CCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CCCC.C(OC1C=CC(C23CCC(CCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CCCCC.C(OC1C=CC(C23CCC(CCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/C.C(OC1C=CC(C23CCC(CCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CC.C(OC1C=CC(C23CCC(CCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CCC.C(OC1C=CC(C23CCC(CCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CCCC.C(OC1C=CC(C23CCC(CCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CCCCC.C(OC1C=CC(C23CCC(CCCCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/C.C(OC1C=CC(C23CCC(CCCCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CC.C(OC1C=CC(C23CCC(CCCCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CCC.C(OC1C=CC(C23CCC(CCCCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CCCC.C(OC1C=CC(C23CCC(CCCCCCC)(CC2)CC3)=C(F)C=1F)(=O)/C=C/CCCCC>>[C:1]([O:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]23[CH2:19][CH2:18][C:17]([CH2:22][CH2:23][CH3:24])([CH2:20][CH2:21]2)[CH2:16][CH2:15]3)=[C:10]([F:25])[C:9]=1[F:26])(=[O:6])/[CH:2]=[CH:3]/[CH3:4]

Participants

Reactant 13

HCID 69962011HCID 69962011, compound

HCID 69962189HCID 69962189, compound

HCID 69962816HCID 69962816, compound

HCID 69962923HCID 69962923, compound

HCID 69962946HCID 69962946, compound

HCID 69963251HCID 69963251, compound

HCID 69963471HCID 69963471, compound

HCID 69963488HCID 69963488, compound

HCID 69963796HCID 69963796, compound

HCID 69963973HCID 69963973, compound

HCID 69964525HCID 69964525, compound

HCID 69964877HCID 69964877, compound

HCID 69990444HCID 69990444, compound

Product 1

HCID 69962512HCID 69962512, compound

Procedure

1-(4-[(E)-Pent-2-enoyloxy]-2, 3-difluorophenyl)-4-propylbicyclo[2.2.2]octane. 1-(4-[(E)-Hept-2-enoyloxy]-2, 3-difluorophenyl)-4-propylbicyclo[2.2.2]octane. 1-(4-[(E)-Oct-2-enoyloxy]-2, 3-difluorophenyl)-4-propylbicyclo[2.2.2]octane. 1-(4-[(E)-But-2-enoyloxy]-2, 3-difluorophenyl)-4-pentylbicyclo[2.2.2]octane. 1-(4-[(E)-Pent-2-enoyloxy]-2, 3-difluorophenyl)-4-pentylbicyclo[2.2.2]octane. 1-(4-[(E)-Hex-2-enoyloxy]-2, 3-difluorophenyl)-4-pentylbicyclo[2.2.2]octane. 1-(4-[(E)-Hept-2-enoyloxy]-2, 3-difluorophenyl)-4-pentylbicyclo[2.2.2]octane. 1-(4-[(E)-Oct-2-enoyloxy]-2, 3-difluorophenyl)-4-pentylbicyclo[2.2.2]octane. 1-(4-[(E)-But-2-enoyloxy]-2, 3-difluorophenyl)-4-heptylbicyclo[2.2.2]octane. 1-(4-[(E)-Pent-2-enoyloxy]-2, 3-difluorophenyl)-4-heptylbicyclo[2.2.2]octane. 1-(4-[(E)-Hex-2-enoyloxy]-2, 3-difluorophenyl)-4-heptylbicyclo[2.2.2]octane. 1-(4-[(E)-Hept-2-enoyloxy]-2, 3-difluorophenyl)-4-heptylbicyclo[2.2.2]octane. 1-(4-[(E)-Oct-2-enoyloxy]-2, 3-difluorophenyl)-4-heptylbicyclo[2.2.2]octane.

Sources & evidence

ORD record: ord-3e915d6b91eb443780bbc438383d7047
Source dataset: uspto-grants-2001_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06187393B1

Reaction notes

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