HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → N-methyl-4-[3-(perfluoro-n-octyl)phenoxy]but-2-enamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Methylamine | HCID 6329 | — |
| Reactant | 1-Bromo-4-[3-(perfluoro-n-octyl)phenoxy]but-2-ene | HCID 86583648 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | N-methyl-4-[3-(perfluoro-n-octyl)phenoxy]but-2-enamine | HCID 86583649 | — |
Reaction Steps
A solution of (1-bromo-4-[3-(perfluoro-n-octyl)phenoxy]but-2-ene (12.9 g) in tetrahydrofuran (20 mL) is added to a solution of 40 wt % methyl amine (20 mL), ethanol (20 mL) and tetrahydrofuran (20 mL) at 40° C. The mixture is stirred at ambient temperature for 2 hr. and extracted in the normal fashion. The resulting oil is Kugelrohr distilled to give N-methyl-4-[3-(perfluoro-n-octyl)phenoxy]but-2-enamine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06194039B1 |
| Source dataset | uspto-grants-2001_02 |
| ORD ID | ord-9b02566b91fa4ba2bf8456da826a6828 |
| Source note | uspto-grants-2001_02 |