Dimethylolpropionic acid → Propanoic acid, 3-hydroxy-2-(hydroxymethyl)-2-methyl-, methyl ester
Reaction equation
[C:1]([C:5]1([CH3:12])[CH2:10][O:9]C(=O)[O:7][CH2:6]1)([O:3][CH3:4])=[O:2].OCC(CO)(C)C(O)=O>CO>[OH:7][CH2:6][C:5]([CH2:10][OH:9])([CH3:12])[C:1]([O:3][CH3:4])=[O:2]Participants
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
As set out hereinabove, the binder component of the dispersion of the invention is an organic polycarbonate polymer. The resulting polymer of the polymerization of 5-carbomethoxy-5-methyl-1,3-dioxan-2-one may be used as a component of the polymer binder. The polycarbonate polymer of 5-carbomethoxy-5-methyl-1,3-dioxan-2-one may be prepared as disclosed in Weilandt, K. D., Keul, H. and Hocker, H., Macromol. Chem. Phys. 197, 3851-3868 (1996). 5-Carbomethoxy-5-methyl-1,3-dioxan-2-one may be prepared via the reaction of 2,2-bis(hydroxymethyl)propionic acid with methanol to give methyl 2,2-bis(hydroxymethyl)propionate, which was then reacted with triphosgene in the presence of triethylamine to afford the desired product, 5-carbomethoxy-5-methyl-1,3-dioxan-2-one, as a white solid.
Sources & evidence
- ORD record
- ord-6bc5da105e894ad2a9a6adadb6cb5404
- Source dataset
- uspto-grants-2001_02
- Patent number
- US06194124B1
Reaction notes
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