HCID 70246066, compound → HCID 53854029, compound

HRID 636535Notes

Reaction equation

HRID 636535 reaction equation
[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][CH:5]=[CH:4][C:3]=1[CH:9]1[C:14]([C:15]([O:17][CH3:18])=[O:16])=[C:13]([CH3:19])[NH:12][C:11]([CH2:20][N:21]2[C:25](=[O:26])[C:24]3=[CH:27][CH:28]=[CH:29][CH:30]=[C:23]3[C:22]2=[O:31])=[C:10]1[C:32]([O:34][CH2:35][CH3:36])=[O:33]>[O-2].[O-2].[Mn+4]>[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][CH:5]=[CH:4][C:3]=1[C:9]1[C:14]([C:15]([O:17][CH3:18])=[O:16])=[C:13]([CH3:19])[N:12]=[C:11]([CH2:20][N:21]2[C:25](=[O:26])[C:24]3=[CH:27][CH:28]=[CH:29][CH:30]=[C:23]3[C:22]2=[O:31])[C:10]=1[C:32]([O:34][CH2:35][CH3:36])=[O:33]

Participants

3

Reactant 1

HCID 70246066HCID 70246066, compound

Product 1

HCID 53854029HCID 53854029, compound

Reagents, catalysts & solvents 1

HCID 178418406HCID 178418406, compoundCatalyst

Procedure

Analogously to the procedure for Example I, 2.3 g (4.3 mmol) of the compound from Example II are oxidized by 10 g of manganese dioxide at RT for 1 h to give 2.0 g (88% of theory) of the title compound.

Sources & evidence

ORD record
ord-0c5aea0bb64c4f18900438d8a6be2fc3
Source dataset
uspto-grants-2001_02
Patent number
US06194428B1

Reaction notes

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