HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloroacetic Acid → N-{[5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrobenzoyloxy]acetyl}-S,S-dimethyl-sulphoximine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloroacetic Acid | HCID 300 | — |
| Reactant | Acifluorfen | HCID 44073 | — |
| Reactant | Sulfoximine, S,S-dimethyl- | HCID 123119 | — |
| Reactant | 1,5-Diazabicyclo(5,4,0)undec-5-ene | HCID 314112 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | N-{[5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrobenzoyloxy]acetyl}-S,S-dimethyl-sulphoximine | HCID 20256529 | — |
Reaction Steps
from chloroacetic acid, dimethyl sulphoximine and 5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrobenzoic acid using 1,5-diaza-bicyclo[5,4,0]undec-5-ene as the base and toluene as the solvent there is obtained N-{[5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrobenzoyloxy]acetyl}-S,S-dimethyl-sulphoximine as a yellow resin; 1H-NMR (CDCl3): 8.23-6.92 (m, 6H), 4.87 (s,2H), 3.37 (s,6H);
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04556413 |
| Source dataset | uspto-grants-1985_12 |
| ORD ID | ord-9305f42870b6419e97d2ce7e86ff2559 |
| Source note | uspto-grants-1985_12 |