HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromopropionic acid → N-{2-[5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrobenzoyloxy]-propionyl}-S,S-dimethyl-sulphoximine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Bromopropionic acid | HCID 11729 | — |
| Reactant | Acifluorfen | HCID 44073 | — |
| Reactant | Sulfoximine, S,S-dimethyl- | HCID 123119 | — |
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Solvent | 1,2-Dimethoxyethane | HCID 8071 | — |
| Product | N-{2-[5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrobenzoyloxy]-propionyl}-S,S-dimethyl-sulphoximine | HCID 20256531 | — |
Reaction Steps
from 2-bromopropionic acid, dimethyl sulphoximine and 5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrobenzoic acid using sodium methylate as the base and 1,2-dimethoxyethane as the solvent there is obtained N-{2-[5-(o-chloro-p-trifluoromethyl-phenoxy)-2-nitrobenzoyloxy]-propionyl}-S,S-dimethyl-sulphoximine as a yellow resin; 1H-NMR (CDCl3): 8.20-6.90 (m,6H), 5.28 (q,1H), 3.37 (s,6H), 1.62 (d,3H);
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04556413 |
| Source dataset | uspto-grants-1985_12 |
| ORD ID | ord-9937dd7690e440d7936fbf3a5184fcf6 |
| Source note | uspto-grants-1985_12 |