Benzene, 2-chloro-1-(3,4-dinitrophenoxy)-4-(trifluoromethyl)- → Dimethyl 2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylthiomethylphosphonate

HRID 637265Notes

Reaction equation

HRID 637265 reaction equation
[Cl:1][C:2]1[CH:20]=[C:19]([C:21]([F:24])([F:23])[F:22])[CH:18]=[CH:17][C:3]=1[O:4][C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[C:7]([N+]([O-])=O)[CH:6]=1.[SH:25][CH2:26][P:27](=[O:32])([O:30][CH3:31])[O:28][CH3:29]>>[N+:11]([C:8]1[CH:9]=[CH:10][C:5]([O:4][C:3]2[CH:17]=[CH:18][C:19]([C:21]([F:24])([F:23])[F:22])=[CH:20][C:2]=2[Cl:1])=[CH:6][C:7]=1[S:25][CH2:26][P:27](=[O:32])([O:30][CH3:31])[O:28][CH3:29])([O-:13])=[O:12]

Participants

3

Reactant 2

HCID 156238Benzene, 2-chloro-1-(3,4-dinitrophenoxy)-4-(trifluoromethyl)-HCID 20490053Dimethyl sulfhydrylmethylphosphonate

Product 1

HCID 13343572Dimethyl 2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylthiomethylphosphonate

Procedure

In like manner, 4-(2-chloro-4-trifluoromethylphenoxy)-1,2-dinitrobenzene and dimethyl sulfhydrylmethylphosphonate is reacted together to yield dimethyl 2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylthiomethylphosphonate.

Sources & evidence

ORD record
ord-4d49952e75b6469f90aaf5e00f7f6893
Source dataset
uspto-grants-1985_12
Patent number
US04556520

Reaction notes

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