HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Azatricyclo[4.3.1.13,8]undecan-5-one → 4-Azatricyclo[4.3.1.13,8]undecane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Azatricyclo[4.3.1.13,8]undecan-5-one | HCID 286647 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 4-Azatricyclo[4.3.1.13,8]undecane | HCID 32272 | — |
Reaction Steps
4-Azatricyclo[4.3.1.13,8 ]undecan-5-one, 2.45 grams (14 mmol), was added to a suspension of lithium aluminum hydride (2.12 grams, 56 mmol) in 200 ml of anhydrous ether. The mixture was refluxed for 6 hours then worked up to give compound 3 as a white solid material recrystallized from hexane (melting point 290° C.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04557865 |
| Source dataset | uspto-grants-1985_12 |
| ORD ID | ord-1499c4e9123a4684905b6ea4d16b8a48 |
| Source note | uspto-grants-1985_12 |