HRID637646

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCC[C@]1(OC(C)=O)CC[C@H]2[C@@H]3CC[C@H]4CC(=O)C[C@H](C)[C@]4(C)[C@H]3CC[C@@]21C

HCID13020886

未命名化合物

结构：CC(C)(C)[O][Al]([O]C(C)(C)C)[O]C(C)(C)C.[H-].[Li+]

HCID16710494

Lithium tri-tert-butoxyaluminohydride

C12H28AlLiO3

PRODUCTS

生成物

结构：CCC[C@]1(OC(C)=O)CC[C@H]2[C@@H]3CC[C@H]4C[C@@H](O)C[C@H](C)[C@]4(C)[C@H]3CC[C@@]21C

HCID70360261

未命名化合物

收率 64.7%

PROCEDURE

实验过程

1.0 g of 17β-acetoxy-1α-methyl-17α-n-propyl-5α-androstan-3-one is reacted as described in Example 6 with lithium tri-tert.-butoxyaluminum hydride and worked up. After chromatography on silica gel, 650 mg of 17β-acetoxy-1α-methyl-17α-n-propyl-5α-androstan-3β-ol is obtained as an oil.