HCID 13547656, compound → 1,1,3-Tris-(3-tert-butyl-4-hydroxy-5-methylphenylthio)butane

HRID 638464Notes

Reaction equation

HRID 638464 reaction equation
[C:1]([C:5]1[CH:6]=[C:7]([S:16][CH:17]([S:37][C:38]2[CH:43]=[C:42]([C:44](C)(C)C)[C:41]([OH:48])=[C:40]([C:49]([CH3:52])([CH3:51])[CH3:50])[CH:39]=2)[CH2:18][CH:19]([S:21][C:22]2[CH:27]=[C:26]([C:28](C)(C)C)[C:25]([OH:32])=[C:24]([C:33]([CH3:36])([CH3:35])[CH3:34])[CH:23]=2)[CH3:20])[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])(C)(C)C.C(C1C=C(SC(C)CC=O)C=C(C)C=1O)(C)(C)C.C(C1C=C(S)C=C(C)C=1O)(C)(C)C>>[C:49]([C:40]1[CH:39]=[C:38]([S:37][CH:17]([S:16][C:7]2[CH:6]=[C:5]([CH3:1])[C:10]([OH:11])=[C:9]([C:12]([CH3:13])([CH3:15])[CH3:14])[CH:8]=2)[CH2:18][CH:19]([S:21][C:22]2[CH:27]=[C:26]([CH3:28])[C:25]([OH:32])=[C:24]([C:33]([CH3:34])([CH3:35])[CH3:36])[CH:23]=2)[CH3:20])[CH:43]=[C:42]([CH3:44])[C:41]=1[OH:48])([CH3:50])([CH3:51])[CH3:52]

Participants

4

Reactant 3

HCID 13547656HCID 13547656, compoundHCID 136435701,1,3-Tris-(3,5-di-tert-butyl-4-hydroxyphenylthio)butaneHCID 136435743-(3-Tert-butyl-4-hydroxy-5-methylphenylthio)butanal

Product 1

HCID 136435751,1,3-Tris-(3-tert-butyl-4-hydroxy-5-methylphenylthio)butane

Procedure

The instant compound named above is made in an analogous manner to the compound of Example 3 by reacting a one molar proportion of reactant (a) with two molar proportions of 2-tert-butyl-6-methyl-4-mercaptophenol. After recrystallization from a solvent mixture of 12:1 heptane: toluene, the compound is isolated as white crystals melting at 65°-69° C.

Workup

  1. customAfter recrystallization
  2. additionfrom a solvent mixture of 12:1 heptane

Sources & evidence

ORD record
ord-63ca6b22284e487781537dcf8938e11b
Source dataset
uspto-grants-1985_12
Patent number
US04560799

Reaction notes

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