Acetone → HCID 13361968, compound

HRID 638546Notes

Reaction equation

HRID 638546 reaction equation
[C:1]1([C:7]([OH:15])([C:11]([NH:13][NH2:14])=[O:12])[C:8]([NH2:10])=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:16][C:17]([CH3:19])=O>>[CH3:16][C:17](=[N:14][NH:13][C:11](=[O:12])[C:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)([OH:15])[C:8]([NH2:10])=[O:9])[CH3:19]

Participants

3

Reactant 2

HCID 180AcetoneHCID 70450031HCID 70450031, compound

Product 1

HCID 13361968HCID 13361968, compound

Procedure

20 g of phenylhydroxymalonic acid amide hydrazide in 100 ml of acetone were heated under reflux for 3 hours. The crystals were filtered off under suction and recrystallized from ethanol. 15 g of phenylhydroxymalonic acid amide (2-propylidene)-hydrazide (m.p. 199°-201° C.) were obtained.

Workup

  1. temperatureunder reflux for 3 hours
  2. filtrationThe crystals were filtered off under suction
  3. customrecrystallized from ethanol

Sources & evidence

ORD record
ord-761d76c4407a445ebb5a3cf79a94d39e
Source dataset
uspto-grants-1985_12
Patent number
US04562185

Reaction notes

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