HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylamine → 2,4-Dimethylspiro[5.5]undeca-1,4,8-trien-3-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylamine | HCID 674 | — |
| Reactant | Formaldehyde | HCID 712 | — |
| Reactant | 1,3-Butadiene | HCID 7845 | — |
| Reactant | 2,6-Dimethylphenol | HCID 11335 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | 2,4-Dimethylspiro[5.5]undeca-1,4,8-trien-3-one | HCID 13531455 | — |
Reaction Steps
Following the same general procedure as in Example I, 50 mmols of 2,6-dimethylphenol were reacted with 55 mmols of paraformaldehyde, 12.5 mmols of aqueous dimethylamine, and 100 mmols of 1,3-butadiene in 54 g of isopropyl alcohol at about 190° C. for 9-10 hours. The process resulted in the formation of 2,4-dimethylspiro[5.5]undeca-1,4,8-trien-3-one.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04562293 |
| Source dataset | uspto-grants-1985_12 |
| ORD ID | ord-47df2dd8f3cf43a28897ee350faee14a |
| Source note | uspto-grants-1985_12 |