HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Butadiene → Spiro[5.5]undeca-1,4,8-trien-3-one, 2,4-bis(1,1-dimethylethyl)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Butadiene | HCID 7845 | — |
| Reactant | Phenol, 4-[(dimethylamino)methyl]-2,6-bis(1,1-dimethylethyl)- | HCID 66609 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | Spiro[5.5]undeca-1,4,8-trien-3-one, 2,4-bis(1,1-dimethylethyl)- | HCID 10730920 | 100% |
Reaction Steps
Following the same general procedure as in Example I, 20 mmols of N,N-dimethyl-4-aminomethyl-2,6-di-t-butylphenol were reacted with approximately 222 mmols of 1,3-butadiene in 47 g of ethyl acetate at about 190° C. for 10 hours. As determined by GC analysis, the process resulted in a 100% yield of 2,4-di-t-butylspiro[5.5]undeca-1,4,8-trien-3-one.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04562294 |
| Source dataset | uspto-grants-1985_12 |
| ORD ID | ord-22957718a0524d56a1a0f2a68722f6fc |
| Source note | uspto-grants-1985_12 |