HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,6-Dimethyl-6-(3-methyl-but-2-enyl)-cyclo-hex-2-enone → 5,7,8,8-Tetramethyl-tricyclo[3.3.1.02,7]nonan-6-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,6-Dimethyl-6-(3-methyl-but-2-enyl)-cyclo-hex-2-enone | HCID 11579258 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 5,7,8,8-Tetramethyl-tricyclo[3.3.1.02,7]nonan-6-one | HCID 68576379 | 49.9% |
Reaction Steps
A solution of 2,6-dimethyl-6-(3-methyl-but-2-enyl)-cyclohex-2-enone (10.0 g, 52.1 mmol) in methanol (250 ml) was irradiated using a Hg-lamp during 3 h. The solvent was evaporated in vacuo and the residue distilled in a Kugelrohr oven to yield 5.0 g of a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07691802B2 |
| Source dataset | uspto-grants-2010_04 |
| ORD ID | ord-d2f05eafb16042a68da946c4e033a095 |
| Source note | uspto-grants-2010_04 |