HuagongsheHuagongshe Chemistry Print Report · For research reference only
Propyltriphenylphosphonium bromide → Methyl 3-(hex-3-en-1-yl)-4,5-dimethoxybenzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Propyltriphenylphosphonium bromide | HCID 80374 | — |
| Reactant | Methyl 3,4-dimethoxy-5-(3-oxopropyl)benzoate | HCID 71378647 | — |
| Product | Methyl 3-(hex-3-en-1-yl)-4,5-dimethoxybenzoate | HCID 68684188 | — |
Reaction Steps
3-Hex-3-enyl-4,5-dimethoxybenzoic acid methyl ester was prepared from 3,4-dimethoxy-5-(3-oxopropyl)benzoic acid methyl ester and propyltriphenylphosphonium bromide by following Method J. The crude product was purified by flash column chromatography on silica gel using 20% EtOAc in hexanes as an eluent to furnish 3-hex-3-enyl-4,5-dimethoxybenzoic acid methyl ester in 63% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07691843B2 |
| Source dataset | uspto-grants-2010_04 |
| ORD ID | ord-de6157c2440949a1819bd617346d3dfe |
| Source note | uspto-grants-2010_04 |