HCID 59256021, compound → HCID 59256046, compound

HRID 639853Notes

Reaction equation

HRID 639853 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([C:9](=[CH2:30])[CH2:10][CH2:11][O:12][Si:13]([C:26]([CH3:29])([CH3:28])[CH3:27])([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:5]=[CH:6][C:7]=1[F:8].N([CH:33]([C:38]([O:40][CH3:41])=[O:39])[C:34]([O:36][CH3:37])=[O:35])=N>>[CH3:37][O:36][C:34]([C:33]1([C:38]([O:40][CH3:41])=[O:39])[CH2:30][C:9]1([C:4]1[CH:5]=[CH:6][C:7]([F:8])=[C:2]([Cl:1])[CH:3]=1)[CH2:10][CH2:11][O:12][Si:13]([C:26]([CH3:29])([CH3:28])[CH3:27])([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)=[O:35]

Participants

3

Reactant 2

HCID 59256021HCID 59256021, compoundHCID 86620198HCID 86620198, compound

Product 1

HCID 59256046HCID 59256046, compound

Procedure

The title compound was prepared in 2.61 g yield starting from {[3-(3-chloro-4-fluorophenyl)-3-buten-1-yl]oxy}(1,1-dimethylethyl)diphenylsilane (P45, 3.624 g) and from dimethyl diazenylpropanedioate (1.98 g) according to a similar procedure described for Preparation 14.

Workup

  1. customyield
  2. customdescribed for Preparation 14

Sources & evidence

ORD record
ord-9724af88bee84be6846164738106eec0
Source dataset
uspto-grants-2010_04
Patent number
US07691893B2

Reaction notes

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